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排序方式: 共有10000条查询结果,搜索用时 31 毫秒
31.
Xian Yang Yu Zhang Xuejie Zhang Jian Chen Haisen Huang Dongsheng Wang Xirong Chai Gening Xie Maxim S. Molokeev Haoran Zhang Yingliang Liu Bingfu Lei 《Journal of the American Ceramic Society》2020,103(3):1773-1781
The red emission with suitable peak wavelength and narrow band is acutely required for high color rendering index (CRI) white LEDs without at the cost of the luminous efficacy. Herein, the Li2Ca2Mg2Si2N6:Eu2+ red phosphor was prepared with facile solid-state method using Ca3N2, Mg3N2, Si3N4, Li3N, and Eu2O3 as the safety raw materials under atmospheric pressure for the first time, which shows red emission peaking at 638 nm with full width at half maximum (FWHM) of 62 nm under blue light irradiation and becomes the desired red phosphor to realize the balance between luminous efficacy and high CRI in white LEDs. The morphology, structure, luminescence properties, thermal quenching behavior, and chromaticity stability of the Li2Ca2Mg2Si2N6:Eu2+ phosphor are investigated in detail. Concentration quenching occurs when the Eu2+ content exceeds 1.0 mol%, whereas high-temperature photoluminescent measurements show a 32% drop from the room-temperature efficiency at 423 K. In view of the excellent luminescence performances of Li2Ca2Mg2Si2N6:Eu2+ phosphor, a white LEDs with CRI of 91 as a proof-of-concept experiment was fabricated by coating the title phosphor with Y3Al5O12:Ce3+ on a blue LED chip. In addition, the potential application of the title phosphor in plant growth LED device was also demonstrated. All the results indicate that Li2Ca2Mg2Si2N6:Eu2+ is a promising red-emitting phosphor for blue LED-based high CRI white LEDs and plant growth lighting sources. 相似文献
32.
Yoshiyuki Watanabe Toru Yahagi Yutaka Abe Hiroki Murayama 《Electrical Engineering in Japan》2019,206(2):54-60
We have fabricated a silicon MEMS resonator aiming at multimodal sensors, and evaluated vibration characteristics by electromagnetic drive and induced electromotive force detection. The resonance frequency of the driving voltage of 0.6 Vpp shows torsional vibration of approximately 87 kHz, and the resonance frequency is shifted toward the low‐frequency side as the driving voltage increases. Resonance characteristics due to temperature change and film stress were evaluated. 相似文献
33.
针对摩擦变形量对异种金属的焊接质量影响情况认识不充分这一问题,开展了摩擦变形量对焊缝组织及力学性能影响规律的研究。基于微观组织、显微硬度和力学性能的对比分析,对调质态42CrMo与正火态36Mn2V管材不同摩擦变形量的连续驱动摩擦焊进行了研究,为其在工程应用提供理论依据。 相似文献
34.
Kenji Imura 《Color research and application》2019,44(5):709-717
The multiwavelength excitation (MWE) method for measuring the colorimetric properties of fluorescent whitening agent (FWA)‐treated specimens illuminated by a standard daylight illuminant computationally approximates not the spectral power distribution (SPD) of the illuminant but the luminescent SPD excited thereby by a weighted sum of the luminescent SPDs excited by a few different narrow‐band illuminations. The weights are optimized for the actual SPDs of those illuminations and the bispectral luminescent radiance factors of typical FWA‐treated paper specimens. Since the latter is invariant among instruments once provided as the common numerical data, the variations of the narrow‐band SPDs give major impacts to the reproducibility of this method. The weights optimized for the varied SPDs, however, mitigate the impacts. For investigating how they impact, one basic illumination system and its 16 simple variation systems were built virtually. The basic system consists of three narrow‐band LEDs and one blue‐excited white LED, whereas the individual simple variation system has either the peak wavelength or spectral width of one of the four LEDs (including the blue LED in the white LED) varied. With those systems, seven FWA‐treated papers with the known bispectral radiance factors were measured computationally by simulating the procedure of the MWE method. The differences in the colorimetric values measured with the simple variation systems from those with the basic system are far below the just noticeable difference, which indicates that the MWE method can be a practical solution for better reproducibility in measuring FWA‐treated papers. 相似文献
35.
Izabela Wysocka Agata Markowska‐Szczupak Piotr Szweda Jacek Ryl Maya Endo‐Kimura Ewa Kowalska Grzegorz Nowaczyk Anna Zieliska‐Jurek 《Indoor air》2019,29(6):979-992
The photocatalytic deactivation of volatile organic compounds and mold fungi using TiO2 modified with mono‐ and bimetallic (Pt, Cu, Ag) particles is reported in this study. The mono‐ and bimetal‐modified (Pt, Cu, Ag) titanium(IV) oxide photocatalysts were prepared by chemical reduction method and characterized using XRD, XPS, DR/UV‐Vis, BET, and TEM analysis. The effect of incident light, type and content of mono‐ and bimetallic nanoparticles deposited on titanium(IV) oxide was studied. Photocatalytic activity of as‐prepared nanocomposites was examined in the gas phase using LEDs array. High photocatalytic activity of Ag/Pt‐TiO2 and Cu/Pt‐TiO2 in the reaction of toluene degradation resulted from improved efficiency of interfacial charge transfer process, which was consistent with the fluorescence quenching effect revealed by photoluminescence (PL) emission spectra. The photocatalytic deactivation of Penicillium chrysogenum, a pathogenic fungi present in the indoor environment, especially in a damp or water‐damaged building using mono‐ and bimetal‐modified (Pt, Cu, Ag) titanium(IV) oxide was evaluated for the first time. TiO2 modified with mono‐ and bimetallic NPs of Ag/Pt, Cu, and Ag deposited on TiO2 exhibited improved fungicidal activity under LEDs illumination than pure TiO2. 相似文献
36.
采用传统的高温固相法合成了Ce3+,Eu2+,Sm3+离子分别单激活和三种稀土离子共激活的Ca6Sr4(Si2O7)3Cl2荧光粉,并通过X射线粉末衍射、荧光光谱和CIE色坐标对其结构和发光性质进行了研究。荧光粉Ca5.91Sr3.96(Si2O7)3Cl2:0.02Ce3+,0.04Eu2+,0.04Sm3+在365 nm激发下能发射高强度白光,其色坐标为x=0.2183,y=0.2187,有望成为一种新型白光LED灯用荧光粉。 相似文献
37.
分析了目前我国煤化工产业发展中存在的问题:创新思维不足,管理、技术、产业结构等方面的创新与产业发展不相匹配;详细阐述了创新驱动包括的多个方面:思维、管理、技术、产业等,指出推进煤化工产业的创新驱动是发展我国煤化工产业最根本、最关键的新动力。 相似文献
38.
39.
为减小电静液伺服系统的流量脉动,提出一种基于主动单向阀与电磁直线执行器的主动配流式电磁直驱静液作动器。建立电磁直线驱动单元和主动单向阀的动力学模型,研究该系统流量脉动和流量大小的特点,分析主动单向阀阀芯结构参数和运动参数对作动系统动态特性的影响。结果表明:减小阀座直径、降低阀芯行程会减小液压缸的最大输入流量;柱塞开始单向行程及到达死点位置的时刻与阀芯运动启闭同步时,系统内不会出现回流并显著减小了流量脉冲现象;与被动配流式电磁直驱静液作动系统相比,主动配流式作动系统能够明显提升系统净流量,抑制系统流量脉动。 相似文献
40.
Tom Neveselý Eva Svobodov Josef Chudoba Marek Sikorski Radek Cibulka 《Advanced Synthesis \u0026amp; Catalysis》2016,358(10):1654-1663
We have developed a metal‐free process for the aerobic photooxygenation of sulfides to sulfoxides mediated by riboflavin tetraacetate or riboflavin (vitamin B2) photocatalysts and visible light (450 nm) in an acetonitrile‐water (85:15 v/v) mixture. The optimised solvent system leads to both singlet‐oxygen and electron‐transfer pathways in photooxygenation, thus allowing oxidation of electron‐poor and electron‐rich thioanisoles, dialkyl sulfides and sterically hindered sulfides. Besides having a broad substrate scope, the method has very short reaction times and requires low catalyst loading (down to 0.1 mol%). These properties are due to the high photocatalyst stability and the extremely high quantum yields (1.3 for thioanisole oxygenation). Moreover, the method is chemoselective, producing only sulfoxides without overoxidation to sulfones. Taking into account the broad substrate scope, high selectivity and high efficiency, this method distinguishes itself from those previously reported. Other advantages include easy work‐up of the reaction mixture, the availability and biodegradability of the photocatalysts and mild reaction conditions. We demonstrated, on a preparative scale, its practical application in the synthesis of the psychostimulant modafinil, in the selective oxidation of methionine derivatives, and in the detoxification of mustard gas.